Asymmetric Hydroformylation

被引：42
|
作者：
Claver, Carmen [1 ]
Dieguez, Montserrat [1 ]
Pamies, Oscar [1 ]
Castillon, Sergio [2 ]
机构：
[1] Univ Rovira & Virgili, Dept Phys Chem & Inorgan Chem, Tarragona 43007, Spain
[2] Univ Rovira & Virgili, Dept Analyt Chem & Organ Chem, Tarragona 43007, Spain
来源：
CATALYTIC CARBONYLATION REACTIONS | 2006年 / 18卷
关键词：
Aldehydes; Catalysis; Enantioselectivity; Hydroformylation; Intermediates; Rhodium;
D O I：
10.1007/3418_016
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This chapter presents the latest achievements reported in the asymmetric hydroformylation of olefins. It focuses on rhodium systems containing diphosphites and phosphine-phosphite ligands, because of their significance in the subject. Particular attention is paid to the mechanistic aspects and the characterization of intermediates in the hydroformylation of vinyl arenes because these are the most important breakthroughs in the area. The chapter also presents the application of this catalytic reaction to vinyl acetate, dihydrofurans and unsaturated nitriles because of its industrial relevance.
引用
收藏
页码：35 / 64
页数：30
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