Synthesis and characterization of polybenzoxazine containing phosphorus

被引：17

作者：

Zhang, Ting-ting ^{[1
]}

Men, Wei-wei ^{[1
]}

Liu, Ying ^{[1
]}

Lu, Zai-jun ^{[1
]}

机构：

[1] Shandong Univ, Key Lab Special Funct Aggregated Mat, Minist Educ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China

来源：

CHINESE JOURNAL OF POLYMER SCIENCE | 2012年 / 30卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Polybenzoxazine; Phosphorus-containing resin; Flame-retardant; Limiting oxygen index; RING-OPENING POLYMERIZATION; ONE-POT SYNTHESIS; FLAME-RETARDANCY; EPOXY-RESINS; BISPHENOL-A; BENZOXAZINES; COMBUSTION; BEHAVIOR; FACILE;

D O I：

10.1007/s10118-012-1115-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The novel benzoxazine monomer containing phosphorus has been synthesized based on multifunctional amine route from bis(4-aminophenyl)phenylphosphate, p-cresol and formaldehyde. Subsequently, the benzoxazine monomer was thermo-cured into polybenzoxazine containing phosphorus. The chemical structures were identified by nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FT-IR). The curing reaction was monitored by differential scanning calorimetry (DSC) and FT-IR. The thermal and flame-retardant properties of obtained polybenzoxazine were evaluated by dynamic mechanical thermal analysis (DMA), thermal gravimetric analysis (TGA) and oxygen index meter, respectively. The results show that the novel polybenzoxazine has high limiting oxygen index (38.1) and glass transition temperature (232A degrees C).

引用

页码：250 / 257

页数：8

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