Gold and silver complexes of methylenebis(diauryldithiocarbamates) and the X-ray structure of CH2[S2CN(CH(2)Ph)(2)](2)

被引：0

作者：

Gimeno, MC

Jambrina, E

Laguna, A

Laguna, M

Murray, HH

Terroba, R

机构：

[1] UNIV ZARAGOZA, CSIC, INST CIENCIA MAT ARAGON, DEPT QUIM INORGAN, ZARAGOZA 50009, SPAIN

[2] UNIV LA RIOJA, DEPT QUIM, LOGRONO 26001, SPAIN

[3] EXXON RES & ENGN CO, CORP RES, ANNANDALE, NJ 08801 USA

来源：

INORGANICA CHIMICA ACTA | 1996年 / 249卷 / 01期

关键词：

crystal structures; gold complexes; silver complexes; dithiocarbamato complexes;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination chemistry of CH2(S(2)CNR(2))(2) for R = Me, Et, n-Bu and benzyl with Au(I), Au(III) and Ag(I) is examined. The single crystal X-ray diffraction study of CH2[S2CN(CH(2)Ph)(2)](2) is described. Nineteen new complexes are characterized by IR, H-1, F-19, P-31 (when appropriate) NMR, elemental analysis, mass spectra (FAB) and conductivity measurements. Neutral and cationic mono- and dinuclear species have been synthesized. The coordination chemistry of CH2(S(2)CNR(2))(2) is via the C = S functionality.

引用

页码：69 / 77

页数：9

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