Adsorption-induced self-organization of calix[4]arene on Au(111) surfaces

被引:0
|
作者
Sakai, T [1 ]
Ohira, A [1 ]
Sakata, M [1 ]
Hirayama, C [1 ]
Kunitake, M [1 ]
机构
[1] Kumamoto Univ, Fac Engn, Dept Appl Chem & Biochem, Kumamoto 8608555, Japan
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The construction and sub-molecular visualization of a self-organized adlayer of calix[4]arene on a Au(111) surface were achieved by potential-controlled adsorption and in situ STM. In situ STM images revealed that the self-organized molecular array consisted of a calix[4]arene dimer. The two molecules in a cone conformation with a sideways orientation were connected in a "head to head" orientation between the hydroxy groups.
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页码:782 / 783
页数:2
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