Crystal structure and luminescence of complexes of Eu(III) and Tb(III) with furan-2,5-dicarboxylate

被引：19

作者：

Akerboom, Sebastiaan ^{[1
]}

Fu, Wen Tian ^{[1
]}

Lutz, Martin ^{[2
]}

Bouwman, Elisabeth ^{[1
]}

机构：

[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands

来源：

INORGANICA CHIMICA ACTA | 2012年 / 387卷

关键词：

Lanthanide; Luminescence; Sensitization; Furan-2,5-dicarboxylate; INTRAMOLECULAR ENERGY-TRANSFER; EUROPIUM; PHOSPHORS; IONS;

D O I：

10.1016/j.ica.2012.01.053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four new Ln(III) complexes (Ln = Eu, Tb) with furan-2,5-dicarboxylic acid (H(2)FDA) as a ligand have been synthesized and characterized in the solid state. Luminescence studies indicate that the compounds exhibit line-like luminescence characteristic of the lanthanide centre upon excitation in the ligand absorption bands. Single crystal X-ray diffraction study of {[Eu(FDA)(H2O)(5)]center dot 1/2(FDA)center dot 3H(2)O}(n) shows the formation of an inorganic polymer with infinite Eu-FDA chains. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：289 / 293

页数：5

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