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Intrinsic and extrinsic x-ray absorption effects in soft x-ray diffraction from the superstructure in magnetite
被引:9
|作者:
Chang, C. F.
[1
]
Schlappa, J.
[1
]
Buchholz, M.
[1
]
Tanaka, A.
[2
]
Schierle, E.
[3
]
Schmitz, D.
[3
]
Ott, H.
[1
]
Sutarto, R.
[1
]
Willers, T.
[1
]
Metcalf, P.
[4
]
Tjeng, L. H.
[1
,5
]
Schuessler-Langeheine, C.
[1
]
机构:
[1] Univ Cologne, Inst Phys 2, D-50937 Cologne, Germany
[2] Hiroshima Univ, ADSM, Dept Quantum Matter, Higashihiroshima 7398530, Japan
[3] Helmholtz Zentrum Berlin Mat & Energie GmbH, D-12489 Berlin, Germany
[4] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA
[5] Max Planck Inst Chem Phys Solids, D-01187 Dresden, Germany
来源:
PHYSICAL REVIEW B
|
2011年
/
83卷
/
07期
关键词:
TRANSITION;
FE3O4;
D O I:
10.1103/PhysRevB.83.073105
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
We studied the (00 1/2) diffraction peak in the low-temperature phase of magnetite (Fe(3)O(4)) using resonant soft x-ray diffraction at the Fe-L(2,3) and O-K resonances. We studied both molecular-beam-epitaxy grown thin films and in situ cleaved single crystals. From the comparison, we have been able to determine quantitatively the contribution of intrinsic absorption effects, thereby arriving at a consistent result for the (00 1/2) diffraction peak spectrum. Our data also allow for the identification of extrinsic effects, e. g., for a detailed modeling of the spectra in case a dead surface layer is present that is only absorbing photons but does not contribute to the scattering signal.
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