The coordination polymer poly[(μ3-3-aminocarbonylpyrazine-2-carboxylato-κ3N1:O2:O2′)silver(I)]

被引：5
|
作者：
Massoud, Al-shima'a A. [1 ]
Langer, Vratislav [1 ]
Abu-Youssef, Morsy A. M. [2 ]
Ohrstrom, Lars [1 ]
机构：
[1] Chalmers Univ Technol, Dept Chem & Biol Engn, SE-41296 Gothenburg, Sweden
[2] Univ Alexandria, Fac Sci, Dept Chem, Alexandria 21321, Egypt
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2011年 / 67卷
关键词：
MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; RETICULAR CHEMISTRY; SILVER(I); DATABASE; NETS;
D O I：
10.1107/S0108270110049875
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Ag(C6H4N3O3)] (n) or [Ag(pyzca)] (n) (where pyzca is 3-aminocarbonylpyrazine-2-carboxylate), (I), was obtained by silver-catalysed partial hydrolysis of pyrazine-2,3-dicarbonitrile in aqueous solution. The compound has a distorted trigonal-planar coordination geometry around the AgI ion, with each ligand bridging three AgI ions to form a one-dimensional strand of molecules parallel to the b axis. An extensive hydrogen-bond pattern connects these strands to form a three-dimensional network of mog topology.
引用
收藏
页码：M1 / M4
页数：4
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