New materials on the basis of amino derivatives of fullerene C60

被引：1
|
作者：
Adamov, J [1 ]
Vojinovic-Miloradov, M [1 ]
机构：
[1] Univ Novi Sad, Inst Chem, YU-21000 Novi Sad, Yugoslavia
来源：
ADVANCED MATERIALS AND PROCESSES: YUCOMAT II | 1998年 / 282-2卷
关键词：
fullerene C-60; addition; amine; optimisation; heat of formation;
D O I：
10.4028/www.scientific.net/MSF.282-283.101
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Electron-deficient molecule C-60 readily undergoes reactions with mines because of their nucleophylic properties. Some monomers and polymers of nitrogen C-60 derivatives have been synthetised. Easy addition of amines is used in synthesis of monomers, as well as polymers of C-60, both in mono-layers and 3D structures. However, their instability does not permit detailed structural studies. In this paper theoretical study of direction of addition to C-60 was done using computational modelling, and the procedure for synthesis of phenyl-hydrazine derivative with free amino group is described. Amino derivatives obtained in these reactions can be important new materials with multiple potential application in medicine, biology and engeneering.
引用
收藏
页码：101 / 107
页数：7
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