Copper-Catalyzed C-H Oxidation/Cross-Coupling of α-Amino Carbonyl Compounds

被引：146
|
作者：
Wu, Ji-Cheng [1 ,2 ]
Song, Ren-Jie [1 ]
Wang, Zhi-Qiang [1 ,2 ]
Huang, Xiao-Cheng [1 ,2 ]
Xie, Ye-Xiang [1 ]
Li, Jin-Heng [1 ]
机构：
[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
[2] Hunan Normal Univ, Minist Educ, Key Lab Chem Biol & Tradit Chinese Med Res, Changsha 410081, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 14期
关键词：
amines; copper; heterocycles; oxidation; synthetic methods; TERMINAL ALKYNES; ASYMMETRIC-SYNTHESIS; OXIDATIVE AMIDATION; AEROBIC OXIDATION; ACID DERIVATIVES; DIRECT ARYLATION; NITROGEN ATOM; BONDS; ESTERS; ARYLGLYCINES;
D O I：
10.1002/anie.201109027
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Keeping options open: The new and mild title reaction involving indoles selectively furnishes 1 and 2 with the aid of tert-butyl hydroperoxide (TBHP). The method represents the first example of a copper-catalyzed α arylation of α-amino carbonyl substrates leading to α-aryl α-imino and α-aryl α-oxo carbonyl compounds using a C-H oxidation strategy. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3453 / 3457
页数：5
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