Carbon Nanotubes-Ionic Liquid and Chloropromazine Modified Electrode for Determination of NADH and Fabrication of Ethanol Biosensor

被引:45
|
作者
Salimi, Abdollah [1 ,2 ]
Lasghari, Sated [1 ]
Noorbakhash, Abdollah [1 ]
机构
[1] Univ Kurdistan, Dept Chem, Sanandaj, Iran
[2] Univ Kurdistan, Res Ctr Nanotechnol, Sanandaj, Iran
关键词
Carbon nanotube; Ionic liquids; Chloropromazine; Alcohol dehydrogenase; Ethanol; Biosensors; LOW POTENTIAL DETECTION; ELECTROCATALYTIC OXIDATION; ALCOHOL-DEHYDROGENASE; ELECTROCHEMICAL SENSORS; VOLTAMMETRIC OXIDATION; AMPEROMETRIC DETECTION; COMPOSITE ELECTRODE; GOLD NANOPARTICLES; FILM; DERIVATIVES;
D O I
10.1002/elan.201000020
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Potential cycling was used I'm oxidation of chloropromazine and producing an electroactive redox couples which strongly adsorbed on the electrode surface modified with carbon nanotubes and ionic liquid nanocomposite The modified electrode shows excellent electrocatalytic activity toward NADH oxidation The differential pulse voltammetry detection provided high sensitivity. 05835 A M. low detection limit. SO nM at concentration range up to 20 mu M An ethanol biosensor was also developed by immobilizing alcohol dehydrogenase enzyme onto nanocomposite Differential pulse voltammetric detection of ethanol gives linear responses over the concentration range 40 mu M-1 5 mM with detection limit 5 Oil and sensitivity I 97 mu A mM(-1)
引用
收藏
页码:1707 / 1716
页数:10
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