Synthesis and structures of fulvene-bridged diruthenium complexes

被引：6

作者：

Ma, Zhi-Hong ^{[2
]}

Liu, Xiao-Huan ^{[1
]}

Han, Zhan-Gang ^{[1
]}

Zheng, Xue-Zhong ^{[1
]}

Lin, Jin ^{[1
]}

机构：

[1] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050016, Peoples R China

[2] Hebei Med Univ, Coll Basic Med, Shijiazhuang 050017, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2011年 / 36卷 / 02期

关键词：

CARBONYL-COMPLEXES; CRYSTAL-STRUCTURE; PENTAFULVENES;

D O I：

10.1007/s11243-010-9455-x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three diruthenium carbonyl complexes, namely (eta (3):eta (5)-C5H4C(CH2)(2))Ru-2(CO)(5) (1), (eta (3):eta (5)-C5H4C(CHCH2)(C2H5))Ru-2(CO)(5) (2), and (eta (1):eta (5)-C5H4C5H8)Ru-2(CO)(6) (3), were obtained from the reactions of C5H4C(Me)(2), C5H4C(Et)(2), and C5H4C(CH2)(4), respectively, with Ru-3(CO)(12) in refluxing xylene. The complexes were characterized by elemental analysis, IR and H-1 NMR spectra. Single-crystal X-ray diffraction analysis for complexes 1 and 2 revealed that the fulvene ligands bridge two ruthenium atoms in eta (3):eta (5) fashion.

引用

页码：207 / 210

页数：4

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