Molecular doped, color-tunable, high-mobility, emissive, organic semiconductors for light-emitting transistors

被引:42
|
作者
Qin, Zhengsheng [1 ,2 ]
Gao, Can [1 ]
Gao, Haikuo [1 ,2 ]
Wang, Tianyu [1 ]
Dong, Huanli [1 ,2 ]
Hu, Wenping [3 ,4 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China
[3] Tianjin Univ, Sch Sci, Tianjin Key Lab Mol Optoelect Sci, Dept Chem, Tianjin 300072, Peoples R China
[4] Haihe Lab Sustainable Chem Transformat, Tianjin 300192, Peoples R China
关键词
AGGREGATION-INDUCED EMISSION; FIELD-EFFECT TRANSISTORS; RECOMBINATION ZONE; EFFICIENCY;
D O I
10.1126/sciadv.abp8775
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Developing high-mobility emissive organic semiconductors with tunable colors is crucial for organic light-emitting transistors (OLETs), a pivotal component of integrated optoelectronic devices, but remains a great challenge. Here, we demonstrate a series of color-tunable, high-mobility, emissive, organic semiconductors via molecular doping with a high-mobility organic semiconductor, 2,6-diphenylanthracene, as the host. The well-matched molecular structures and sizes with efficient energy transfer between the host and guest enable the intrinsically high charge transport with tunable colors. High mobility with the highest value >2 cm(2) V-1 s(-1) and strong emission with photoluminescence quantum yield >15.8% are obtained for these molecular-doped organic semiconductors. Last, a large color gamut for constructed OLETs is up to 59% National Television System Committee standard, meanwhile with an extremely high current density approaching 326.4 kA cm(-2), showing great potential for full-color smart display, organic electrically pumped lasers and other related logic circuitries.
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页数:8
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