Enhanced CO2 absorption of poly(ionic liquid)s

被引：260
|
作者：
Tang, JB
Sun, WL
Tang, HD
Radosz, M
Shen, YQ [1 ]
机构：
[1] Univ Wyoming, Dept Chem & Petroleum Engn, Laramie, WY 82071 USA
[2] Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou, Peoples R China
来源：
MACROMOLECULES | 2005年 / 38卷 / 06期
关键词：
D O I：
10.1021/ma047574z
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The CO 2 absorption capacity of the polymers from ionic liquids which was much higher than room temperature ionic liquid was discussed. The polymers poly[1-(4-vinylbenzyl)-3-butylimidazolium tetrafluoroborate] (PVBIT), poly[(1-(4-vinylbenzyl)-3-butylimidazolium hexafluorophosphate] (PVBIH) and poly[2-(1-butylimidazolium-3-yl)ethyl methacrylate tetrafluoroborate] (PBIMT) were prepared from their corresponding ionic liquid monomers. It took four minutes for PVBIT and PVBIH and three minutes for PBIMT to reach their 90% sorption capacities. Analysis shows that the CO 2 absorption capacity of the polymers is due to the interaction of the imidazolium tetrafluoroborate moiety with CO 2.
引用
收藏
页码：2037 / 2039
页数：3
相关论文
共 50 条
  • [21] Synthesis of porous poly(ionic liquid)s for chemical CO2 fixation with epoxides
    Li, Guoqing
    Dong, Shu
    Fu, Ping
    Yue, Qihong
    Zhou, Yu
    Wang, Jun
    GREEN CHEMISTRY, 2022, 24 (09) : 3433 - 3460
  • [22] Enhanced CO2 Absorption in Organic Solutions of Biobased Ionic Liquids
    Davarpanah, Elahe
    Hernandez, Simelys
    Latini, Giulio
    Pirri, Candido Fabrizio
    Bocchini, Sergio
    ADVANCED SUSTAINABLE SYSTEMS, 2020, 4 (01)
  • [23] Very fast CO2 response and hydrophobic properties of novel poly(ionic liquid)s
    Mineo, Placido G.
    Livoti, Letizia
    Giannetto, Marco
    Gulino, Antonino
    Lo Schiavo, Sandra
    Cardiano, Paola
    JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (46) : 8861 - 8870
  • [24] Imidazolium-Based Poly(ionic liquid)s as New Alternatives for CO2 Capture
    Privalova, Elena I.
    Karjalainen, Erno
    Nurmi, Mari
    Maki-Arvela, Paivi
    Eranen, Kari
    Tenhu, Heikki
    Murzin, Dmitry Yu.
    Mikkola, Jyri-Pekka
    CHEMSUSCHEM, 2013, 6 (08) : 1500 - 1509
  • [25] CO2 absorption and kinetic study in ionic liquid amine blends
    Haider, Md Belal
    Hussain, Zakir
    Kumar, Rakesh
    JOURNAL OF MOLECULAR LIQUIDS, 2016, 224 : 1025 - 1031
  • [26] Cellulosic poly(ionic liquid)s: synthesis, characterization and application in the cycloaddition of CO2 to epoxides
    Chen, Qin
    Peng, Chang
    Xie, Haibo
    Zhao, Zongbao Kent
    Bao, Ming
    RSC ADVANCES, 2015, 5 (55): : 44598 - 44603
  • [27] Intensification of dimethyaminoethoxyethanol on CO2 absorption in ionic liquid of amino acid
    Zhang, Feng
    Gao, Kai-Xuan
    Meng, Yu-Ning
    Qi, Min
    Geng, Jiao
    Wu, You-Ting
    Zhang, Zhi-Bing
    INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL, 2016, 51 : 415 - 422
  • [28] Enthalpic Driving Force for the Selective Absorption of CO2 by an Ionic Liquid
    Daly, Clyde A., Jr.
    Brinzer, Thomas
    Allison, Cecelia
    Garrett-Roe, Sean
    Corcelli, Steven A.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2018, 9 (06): : 1393 - 1397
  • [29] Synthesis, CO2 sorption and capacitive properties of novel protic poly(ionic liquid)s
    Cardiano, Paola
    Gomez-Laserna, Olivia
    Mineo, Placido G.
    Furia, Emilia
    Triolo, Claudia
    Patane, Salvatore
    Lo Schiavo, Sandra
    JOURNAL OF MOLECULAR LIQUIDS, 2017, 241 : 222 - 230
  • [30] Mechanistic insights on ionic liquid and poly(ionic liquid) solutions for CO2 capture and cycloaddition reactions
    Barrulas, Raquel, V
    Barao, Rodrigo M.
    Bernardes, Carlos E. S.
    Zanatta, Marcileia
    Corvo, Marta C.
    CARBON CAPTURE SCIENCE & TECHNOLOGY, 2025, 15
12345