Highly efficient copper-catalyzed nitro-mannich type reaction:: Cross-dehydrogenative-coupling between sp3 C-H bond and sp3 C-H bond

被引：516
|
作者：
Li, ZP [1 ]
Li, CJ [1 ]
机构：
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 11期
关键词：
D O I：
10.1021/ja050058j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel C-C bond formation method was developed via the cross-dehydrogenative-coupling (CDC) reaction catalyzed by using copper bromide in the presence of an oxidizing reagent, tert-BuOOH. The CDC reaction provides a simple and efficient catalytic method to construct β-nitroamine via the reaction between sp3 C-H and sp3 C-H bonds. Copyright © 2005 American Chemical Society.
引用
收藏
页码：3672 / 3673
页数：2
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