Intermolecular atom transfer radical addition of α,α,α-trichloromethyl ketones and alkenes mediated by a CuCl/bpy system

被引：7
|
作者：
Rexit, Abulikernu Abudu [1 ,2 ]
Hu, Xiangdong [1 ]
机构：
[1] Northwest Univ, Dept Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ China, Xian 710069, Peoples R China
[2] Xinjiang Normal Univ, Dept Chem, Urumqi 830054, Peoples R China
来源：
TETRAHEDRON | 2015年 / 71卷 / 15期
基金：
中国国家自然科学基金;
关键词：
Alkenes; Addition; Atom transfer; Copper; Ketones; CYCLIZATION REACTIONS; POLYHALOALKANES; OLEFINS;
D O I：
10.1016/j.tet.2015.01.021
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An atom transfer radical addition reaction between a,a,a-trichloromethyl ketones and alkenes mediated by a CuCl/bpy system is reported, which presents a good example of intermolecular atom transfer radical addition reactions. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2313 / 2316
页数：4
相关论文
共 50 条
  • [21] Iron-Catalyzed Radical Intermolecular Addition of Unbiased Alkenes to Aldehydes
    Saladrigas, Mar
    Puig, Jordi
    Bonjoch, Josep
    Bradshaw, Ben
    ORGANIC LETTERS, 2020, 22 (20) : 8111 - 8115
  • [22] RADICAL-ADDITION TO AMIDE-SUBSTITUTED ALKENES - STEREOSELECTIVE INTERMOLECULAR RADICAL ADDITIONS
    PORTER, NA
    SCOTT, DM
    LACHER, B
    GIESE, B
    ZEITZ, HG
    LINDNER, HJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (21) : 8311 - 8312
  • [23] Atom-Transfer Radical Addition to Unactivated Alkenes by using Heterogeneous Visible-Light Photocatalysis
    Mao, Liang-Liang
    Cong, Huan
    CHEMSUSCHEM, 2017, 10 (22) : 4461 - 4464
  • [24] Photoinduced Atom Transfer Radical Addition/Cyclization Reaction between Alkynes or Alkenes with Unsaturated α-Halogenated Carbonyls
    Matsuo, Kazuki
    Yoshitake, Tadashi
    Yamaguchi, Eiji
    Itoh, Akichika
    MOLECULES, 2021, 26 (22):
  • [25] Metal-free Photochemical Atom Transfer Radical Addition (ATRA) of BrCCl3 to Alkenes
    Nikitas, Nikolaos F.
    Voutyritsa, Errika
    Gkizis, Petros L.
    Kokotos, Christoforos G.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 2021 (01) : 96 - 101
  • [26] Acetal Addition to Electron-Deficient Alkenes with Hydrogen Atom Transfer as a Radical Chain Propagation Step
    Chan, Wei Chuen
    Vinod, Jincy K.
    Koide, Kazunori
    JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (04): : 3674 - 3682
  • [27] A new complex catalytic system CuX/bpy/Al(OR)3 for atom transfer radical polymerization
    Guo, JH
    Han, ZW
    Wu, PP
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 159 (01) : 77 - 83
  • [28] Synthesis of Ketones and Esters from Heteroatom-Functionalized Alkenes by Cobalt-Mediated Hydrogen Atom Transfer
    Ma, Xiaoshen
    Herzon, Seth B.
    JOURNAL OF ORGANIC CHEMISTRY, 2016, 81 (19): : 8673 - 8695
  • [29] Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System
    Kostromitin, Vladislav S.
    Levin, Vitalij V.
    Dilman, Alexander D.
    CATALYSTS, 2023, 13 (07)
  • [30] Light-activation of SF5Cl for the atom transfer radical addition onto alkenes and alkynes
    Berger, Marie-Rose Ouellet-Du
    Boucher, Maxim
    Paquin, Jean-Francois
    JOURNAL OF FLUORINE CHEMISTRY, 2023, 268
12345