Study on co-pyrolysis and products of Chlorella vulgaris and rice straw catalyzed by activated carbon/HZSM-5 additives

被引:11
|
作者
Chen, Chunxiang [1 ,2 ,3 ]
Wei, Dening [1 ]
Zhao, Jian [1 ]
Huang, Xiaodong [1 ]
Fan, Dianzhan [1 ]
Qi, Qianhao [1 ]
Bi, Yingxing [1 ]
Liao, Liping [1 ]
机构
[1] Guangxi Univ, Coll Mech Engn, Univ Rd 100, Nanning 530004, Peoples R China
[2] Guangxi Key Lab Petrochem Resources Proc & Proc In, Nanning 530004, Peoples R China
[3] Guangdong Prov Key Lab Efficient & Clean Energy Ut, Guangzhou 510640, Peoples R China
关键词
Microwave -assisted catalytic co -pyrolysis; Compound additives; Bio-oil; Activated carbon; HZSM-5; MICROWAVE-ASSISTED PYROLYSIS; DOUGLAS-FIR SAWDUST; BIO-OIL; LIGNOCELLULOSIC BIOMASS; MICROALGAE; ZEOLITES; PHENOLS; SLUDGE;
D O I
10.1016/j.biortech.2022.127594
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The weight loss characteristics, product distribution and bio-oil composition of co-pyrolysis of rice straw (RS) and Chlorella vulgaris (CV) were investigated by microwave oven. Then, the catalytic effect of activated carbon (AC) and HZSM-5 on these characteristics were studied. Results showed that AC strongly improved co-pyrolysis weight loss characteristics and obtained maximum average weight loss rate (Ra) at 30% addition with 0.01639 wt.%/s. While HZSM-5 promoted the characteristics as addition was lower than 10%. In the case of compound additives, 20% A7H3 obtained the maximum Ra (0.01413 wt.%/s). Furthermore, both single AC and HZSM-5 showed negative effect on bio-oil production, while 20% A7H3 (AC/HZSM-5 = 7:3) achieved the maximum production (24%). For bio-oil composition, 30% A10H0 showed strong selectivity for phenol and N-heterocycle and 10% A0H10 showed strong aromatization capacity, and the addition of 20% A7H3 increased the hydrocarbons content from 20.79% to 31.63% compared with the blank group.
引用
收藏
页数:10
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