Nonuniqueness of generalized quantum master equations for a single observable

被引:11
|
作者
Ng, Nathan [1 ]
Limmer, David T. [2 ,3 ,4 ,5 ]
Rabani, Eran [2 ,4 ,6 ]
机构
[1] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Kavli Energy NanoSci Inst, Berkeley, CA 94720 USA
[4] Lawrence Berkeley Natl Lab, Mat Sci Div, Berkeley, CA 94720 USA
[5] Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA
[6] Tel Aviv Univ, Sackler Ctr Computat Mol & Mat Sci, IL-69978 Tel Aviv, Israel
来源
JOURNAL OF CHEMICAL PHYSICS | 2021年 / 155卷 / 15期
关键词
Systems analysis;
D O I
10.1063/5.0068331
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
When deriving exact generalized master equations for the evolution of a reduced set of degrees of freedom, one is free to choose what quantities are relevant by specifying projection operators. However, obtaining a reduced description does not always need to be achieved through projections-one can also use conservation laws for this purpose. Such an operation should be considered as distinct from any kind of projection; that is, projection onto a single observable yields a different form of master equation compared to that resulting from a projection followed by the application of a constraint. We give a simple example to show this point and give relationships that the different memory kernels must satisfy to yield the same dynamics.
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页数:3
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