Optimization of cation structure of imidazolium-based ionic liquids as ionic solvents for rechargeable magnesium batteries

被引：62
|
作者：
Kakibe, Takeshi [1 ,2 ]
Yoshimoto, Nobuko [1 ,2 ]
Egashira, Minato [1 ]
Morita, Masayuki [1 ,2 ]
机构：
[1] Yamaguchi Univ, Dept Appl Chem, Grad Sch Sci & Engn, Ube, Yamaguchi 7558611, Japan
[2] Japan Sci & Technol Agcy JST, CREST, Kawaguchi, Saitama 3220012, Japan
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2010年 / 12卷 / 11期
关键词：
Magnesium battery; Ionic liquid; Substituted imidazolium cation; Structure optimization; Methyl magnesium bromide; Cathodic deposition; DEPOSITION; ELECTROCHEMISTRY; PROGRESS;
D O I：
10.1016/j.elecom.2010.09.012
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A series of imidazolium cation-based ionic liquids (ILs) have been synthesized and examined as ionic solvents for rechargeable magnesium batteries. The electrolyte solutions consist of these ILs dissolving methylmagnesium bromide with tetrahydrofuran (MeMgBr/THF). The chemical structure of imidazolium cation much influenced the ionic conductivity and the electrochemical window of the system. A reversible process of cathodic deposition and anodic dissolution of magnesium has been successfully achieved at room temperature. The highest value of anodic peak current for magnesium dissolution was obtained in an optimized-structure IL with allyl and methoxyethyl groups as the substituents. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：1630 / 1633
页数：4
相关论文
共 50 条
  • [31] Actinide and lanthanide speciation in imidazolium-based ionic liquids
    Billard, I.
    Gaillard, C.
    RADIOCHIMICA ACTA, 2009, 97 (07) : 355 - 359
  • [32] A reversal from endothermic to exothermic behavior of imidazolium-based ionic liquids in molecular solvents
    Rai, Gitanjali
    Kumar, Anil
    CHEMICAL PHYSICS LETTERS, 2010, 496 (1-3) : 143 - 147
  • [33] Revisited vibrational assignments of imidazolium-based ionic liquids
    Grondin, Joseph
    Lassegues, Jean-Claude
    Cavagnat, Dominique
    Buffeteau, Thierry
    Johansson, Patrik
    Holomb, Roman
    JOURNAL OF RAMAN SPECTROSCOPY, 2011, 42 (04) : 733 - 743
  • [34] Local solvent properties of imidazolium-based ionic liquids
    Veldhorst, Arno A.
    Faria, Luiz F. O.
    Ribeiro, Mauro C. C.
    JOURNAL OF MOLECULAR LIQUIDS, 2016, 223 : 283 - 288
  • [35] Imidazolium-based chiral ionic liquids: synthesis and application
    Suzuki, Yumiko
    Wakatsuki, Junichiro
    Tsubaki, Mariko
    Sato, Masayuki
    TETRAHEDRON, 2013, 69 (46) : 9690 - 9700
  • [36] Palladium catalysed hydroethoxycarbonylation in imidazolium-based ionic liquids
    Rangits, G
    Kollár, L
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 246 (1-2) : 59 - 64
  • [37] Imidazolium-based ionic liquids grafted on solid surfaces
    Xin, Bingwei
    Hao, Jingcheng
    CHEMICAL SOCIETY REVIEWS, 2014, 43 (20) : 7171 - 7187
  • [38] The thermochemistry of solvation of imidazolium-based ionic liquids in benzene
    Khachatrian, Artashes A.
    Solomonov, Boris N.
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2020, 58 (01) : 70 - 76
  • [39] Surface characterization of functionalized imidazolium-based ionic liquids
    Kolbeck, Claudia
    Killian, Manuela
    Maier, Florian
    Paape, Natalia
    Wasserscheid, Peter
    Steinrueck, Hans-Peter
    LANGMUIR, 2008, 24 (17) : 9500 - 9507
  • [40] Impact of the cation symmetry on the mutual solubilities between water and imidazolium-based ionic liquids
    Martins, Monia A. R.
    Neves, Catarina M. S. S.
    Kurnia, Kiki A.
    Luis, Andreia
    Santos, Luis M. N. B. F.
    Freire, Mara G.
    Pinho, Simao P.
    Coutinho, Joao A. P.
    FLUID PHASE EQUILIBRIA, 2014, 375 : 161 - 167
12345