Copper(ii) and manganese(ii) complexes based on a new N,O-chelating ligand bearing the 1,3,5-diazaphosphorinane moiety

被引：10

作者：

Trigulova, K. R. ^{[1
]}

Shamsieva, A., V ^{[1
]}

Kasimov, A., I ^{[1
]}

Litvinov, I. A. ^{[1
]}

Amerhanova, S. K. ^{[1
]}

Voloshina, A. D. ^{[1
]}

Musina, E., I ^{[1
]}

Karasik, A. A. ^{[1
]}

机构：

[1] Russian Acad Sci, FRC Kazan Sci Ctr, Arbuzov Inst Organ & Phys Chem, 8 Ul Akad Arbuzova, Kazan 420088, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2022年 / 71卷 / 07期

关键词：

diazaphosphorinane; pyridyl-containing phosphine oxides; N; O-chelating ligands; Cu-II complexes; Mn-II complexes; cytotoxicity; molecular structure; X-ray diffraction analysis; METAL-COMPLEXES; IN-VITRO; CRYSTAL-STRUCTURES; DNA; CLEAVAGE; CU(II);

D O I：

10.1007/s11172-022-3547-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper(ii) and manganese(ii) chelate complexes were synthesized using the new N,O-hybrid ligand 1,3-dibenzhydryl-5-(pyridin-2-yl)-1,3,5-diazaphosphinane 5-oxide. The synthesized complexes were characterized by physicochemical methods. The molecular and crystal structures of the complexes were established by X-ray diffraction. All new compounds were evaluated for cytotoxicity against the cancer cell lines M-HeLa and HuTu80 and the normal cell line Chang liver.

引用

页码：1410 / 1421

页数：12

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