A high-performance and stable Cu/Beta for adsorption-catalytic oxidation in-situ destruction of low concentration toluene

被引：29
|
作者：
Du, Yueying [1 ]
Xiao, Gaofei [1 ]
Guo, Ziyang [1 ]
Lin, Beilong [1 ]
Fu, Mingli [1 ,2 ,3 ]
Ye, Daiqi [1 ,2 ,3 ]
Hu, Yun [1 ,2 ,3 ]
机构：
[1] South China Univ Technol, Sch Environm & Energy, Guangzhou 510006, Peoples R China
[2] Guangdong Prov Key Lab Atmospher Environm & Pollut, Guangzhou 510006, Peoples R China
[3] Minist Educ, Key Lab Pollut Control & Ecosyst Restorat Ind Clus, Guangzhou 510006, Peoples R China
来源：
SCIENCE OF THE TOTAL ENVIRONMENT | 2022年 / 833卷
关键词：
Cu; Beta; Toluene; Adsorption-catalytic oxidation integration; VOLATILE ORGANIC-COMPOUNDS; ACTIVATED CARBON; ZEOLITE; OXIDES; CHLOROBENZENE; REMOVAL;
D O I：
10.1016/j.scitotenv.2022.155288
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Finding a cost-effective treatment to remove of low concentrations of volatile organic compounds (VOCs) is still a challenge. In this study, a Cu/Beta material was developed for in situ adsorption-catalytic oxidation of low concentrations of toluene. The results showed that the addition of Cu enhanced the adsorption and catalytic oxidation of toluene by Beta zeolite. Cu7/Beta with a Cu+ ratio of close to 50% performed best. The high adsorption of Cu7/Beta was mainly attributed to the abundant Cu+ species and the micro-mesoporous structure of the Beta zeolite, and the high catalytic oxidation was attributed to the lattice oxygen in the uniformly dispersed CuO. Finally, the adsorption intermediates and reaction pathways in the catalytic oxidation of toluene were clarified using XPS and DRIFTS spectra. This work provides new strategies for the development of efficient and stable adsorption-catalytic oxidation in situ destruction materials.
引用
收藏
页数：12
相关论文
共 50 条
  • [41] Steering in-situ low-voltage phase transition from spinel to layered cathode for high-performance zinc-ion batteries
    Luo, Dan
    He, Hanna
    Zeng, Li
    Yu, Huaibo
    Li, Xiaolong
    Zhang, Chuhong
    ENERGY STORAGE MATERIALS, 2024, 67
  • [42] A Cu(111) supported h-BN nanosheet: a potential low-cost and high-performance catalyst for CO oxidation
    Lin, Sen
    Huang, Jing
    Gao, Xiaomei
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (34) : 22097 - 22105
  • [43] Self-catalytic approach to construct graphitized carbon shell for metal oxide: In-situ triggering mechanism and high-performance lithium-ion batteries applications
    Sun, Qujiang
    Wang, Shaohua
    Ming, Hai
    Zhou, Lin
    Wu, Yingqiang
    Xue, Hongjin
    Wang, Limin
    Ming, Jun
    JOURNAL OF POWER SOURCES, 2020, 450
  • [44] Cu/CuFe2O4 integrated graphite felt as a stable bifunctional cathode for high-performance heterogeneous electro-Fenton oxidation
    Cui, Lele
    Li, Zhiwen
    Li, Qingqing
    Chen, Meifei
    Jing, Wenheng
    Gu, Xuehong
    CHEMICAL ENGINEERING JOURNAL, 2021, 420
  • [45] Hierarchical MoO3-MnNi LDH@Cu(OH)2 Core-Shell Nanorod Arrays Constructed through In-Situ Oxidation Combined with a Hydrothermal Strategy for High-Performance Energy Storage
    Cheng, Wenting
    Huang, Wenjun
    Zhang, Aitang
    Du, Yiqi
    Cui, Liang
    Tian, Pengfei
    Liu, Jingquan
    CHEMELECTROCHEM, 2022, 9 (24)
  • [46] Economical and simple in-situ synthesis of CuS@Cu foam as a binder-free cathode for high-performance hybrid Mg-Li ion batteries
    Liu, Yang
    Yang, Jingdong
    Wen, Jiaxin
    Ye, Junliu
    Liu, Huan
    Lu, Liwei
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2024, 35 (17)
  • [47] Fabrication of high-performance CeO2-MnOx/TiO2/Ti monolithic catalysts for low-temperature and stable CO oxidation
    Wang, Junchao
    Tang, Xinyue
    Li, Jing
    Dong, Shizhi
    Zhang, Xinglai
    Liu, Baodan
    CATALYSIS SCIENCE & TECHNOLOGY, 2023, 13 (11) : 3386 - 3394
  • [48] One-Step Synthesis of a Binder-Free, Stable, and High-Performance Electrode; Cu-O|Cu3P Heterostructure for the Electrocatalytic Methanol Oxidation Reaction (MOR)
    Yarmolenko, Alina
    Malik, Bibhudatta
    Avraham, Efrat Shawat
    Nessim, Gilbert Daniel
    NANOMATERIALS, 2023, 13 (07)
  • [49] Metal-organic framework-derived in situ-grown Cu2Sb@NC octahedra for high-performance stable lithium/sodium storage
    Zhu, Bing
    Liu, Yangai
    Liu, Yicen
    Wu, Liming
    Zhang, Xi
    CHEMICAL ENGINEERING JOURNAL, 2024, 500
  • [50] In-situ grown Ti3C2@TiO2 heterostructure enables high-performance lithium-sulfur batteries with polysulfides capture and catalytic conversion mechanism
    不详
    JOURNAL OF CENTRAL SOUTH UNIVERSITY, 2024, 31 (12) : 4397 - 4410
12345