Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4

被引：9

作者：

Loginov, Dmitry A. ^{[1
]}

Pronin, Andrei A. ^{[1
]}

Starikova, Zoya A. ^{[1
]}

Petrovskii, Pavel V. ^{[1
]}

Kudinov, Alexander R. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2010年 / 20卷 / 05期

关键词：

TRIPLE-DECKER COMPLEXES; (TETRAMETHYLCYCLOBUTADIENE)COBALT COMPLEXES; BOROLE DERIVATIVES; FRAGMENT;

D O I：

10.1016/j.mencom.2010.09.010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Visible-light irradiation of the cation [(eta-C4H4BOH)Co(eta-C6H6)](+) in the presence of alkyl-substituted benzenes in CH2Cl2 results in arene exchange giving [(eta-C4H4BOH)Co(eta-C6R6)](+) (C6R6 = toluene, p-xylene or mesitylene); the structure of [(eta-C4H4BOH)Co(eta-mesitylene)]BF4 was confirmed by X-ray diffraction

引用

页码：271 / 272

页数：2

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