Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4

被引：9
|
作者：
Loginov, Dmitry A. [1 ]
Pronin, Andrei A. [1 ]
Starikova, Zoya A. [1 ]
Petrovskii, Pavel V. [1 ]
Kudinov, Alexander R. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2010年 / 20卷 / 05期
关键词：
TRIPLE-DECKER COMPLEXES; (TETRAMETHYLCYCLOBUTADIENE)COBALT COMPLEXES; BOROLE DERIVATIVES; FRAGMENT;
D O I：
10.1016/j.mencom.2010.09.010
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Visible-light irradiation of the cation [(eta-C4H4BOH)Co(eta-C6H6)](+) in the presence of alkyl-substituted benzenes in CH2Cl2 results in arene exchange giving [(eta-C4H4BOH)Co(eta-C6R6)](+) (C6R6 = toluene, p-xylene or mesitylene); the structure of [(eta-C4H4BOH)Co(eta-mesitylene)]BF4 was confirmed by X-ray diffraction
引用
收藏
页码：271 / 272
页数：2
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