Solvothermal synthesis and properties of three antimony chalcogenides containing transition metal zinc

被引：8
|
作者：
Shele, Muge [1 ]
Tian, Xinyu [1 ]
Baiyin, Menghe [1 ]
机构：
[1] Inner Mongolia Normal Univ, Coll Chem & Environm Sci, Hohhot 010022, Inner Mongolia, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2021年 / 302卷
基金：
中国国家自然科学基金;
关键词：
Solvothermal synthesis; Properties; CRYSTAL-STRUCTURE; BAND-GAP; FE; TM; THIOANTIMONATES(III); PHOTOCURRENT; SULFIDE; CHAINS; SE; MN;
D O I：
10.1016/j.jssc.2021.122401
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three antimony chalcogenides containing transition metal zinc ions were successfully prepared by solvent method, namely, [Zn(tren)(2)H]SbSe4 (1) [tren =tris (2 - aminoethyl) amine)], [Ni(1, 2-dap)(3)](2)Zn(1, 2-dap)Sb2Se8 (2) (1, 2 - dap = 1, 2 - diaminopropane) and Rb2ZnSb4S8 (3). Interestingly, the Zn2+ ion in compound 1 is a trigonal-bipyramidal structure, while in compounds 2 and 3 it is a tetrahedral structure. The optical and photoelectric properties of compounds 1-3 were studied. In addition, the magnetic of compound 2 was studied.
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页数：8
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