A water-stable lanthanide-coordination polymer with free Lewis site for fluorescent sensing of Fe3+

被引：19

作者：

Wang, Wenhe ^{[1
]}

Gao, Qiang ^{[2
]}

Li, Xiaoyu ^{[2
]}

Wang, Jianhong ^{[1
]}

Wang, Chaopeng ^{[2
]}

Zhang, Yinghui ^{[2
]}

Bu, Xianhe ^{[1
,2
]}

机构：

[1] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Dept Chem, Tianjin 300071, Peoples R China

[2] Nankai Univ, TKL Metal & Mol Based Mat Chem, Sch Mat Sci & Engn, Tianjin 300350, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2019年 / 30卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Lanthanide-based coordination polymers; Fluorescent sensing; Aqueous solution; Lewis site; Iron ion; METAL-ORGANIC FRAMEWORKS; BASIC PYRIDYL SITES; SELECTIVE DETECTION; LUMINESCENT; IONS; SENSOR; FE(III); PROBE; FE2+; MOF;

D O I：

10.1016/j.cclet.2018.06.014

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new fluorescent coordination polymer (NICU 115) was constructed under solvothermal condition based on Tb3+ ion and H2L(5-(4H-1,2,4-triazol-4-yl) benzene-1,3-dicarboxylic acid) ligand, featuring high solvent and water stability. Luminescent investigations revealed that NKU-115 shows fluorescence quenching response toward Fe3+ in aqueous solution and the mechanism of quenching was analyzed. (C) 2018 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

引用

页码：75 / 78

页数：4

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