Sonochemical synthesis of the high energy density cathode material VOPO4•2H2O

被引：33
|
作者：
Park, NG [1 ]
Kim, KM [1 ]
Chang, SH [1 ]
机构：
[1] Elect & Telecommun Res Inst, Telecommun Basic Res Lab, Taejon 305350, South Korea
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2001年 / 3卷 / 10期
关键词：
sonochemical; vanadyl phosphate dihydrate; lithium battery; cathode; high energy density;
D O I：
10.1016/S1388-2481(01)00217-X
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
We report on a high energy density VOPO4. 2H(2)O cathode material prepared by the sonochemical method. VOPO4. 2H(2)O is rapidly prepared within 15 min by ultrasonic irradiation of an aqueous solution containing V2O5 and H3PO4. The sonochemically synthesized VOPO4. 2H(2)O forms rectangular polycrystals 1-3 tm in size as observed by transmission electron microscopy (TEM) and selected area electron diffraction. X-ray diffraction (XRD) and Fourier transformed infrared (FTIR) spectroscopic studies confirmed the phase purity. The electrochemical test of the sonochemically synthesized VOPO4. 2H(2)O in a nonaqueous Li salt electrolyte showed a cell voltage of 3.6 V and an energy density of 486 Wh/kg, along with a good reversibility for lithium insertion/extraction. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：553 / 556
页数：4
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