Palladium-Catalyzed Ligand-Free Suzuki-Miyaura Reaction of Aryl Fluorosulfates and Various Arylboron Compounds

被引：8

作者：

Li, Xinmin ^{[1
]}

Zhang, Hang ^{[1
]}

Feng, Fangfang ^{[1
]}

Hu, Qinghong ^{[1
]}

Yuan, Zeli ^{[1
]}

机构：

[1] Zunyi Med Univ, Sch Pharm, Zunyi 563000, Peoples R China

来源：

CHEMISTRYSELECT | 2018年 / 3卷 / 43期

关键词：

Arylboron Compounds; Aryl Fluorosulfate; Ligand-free; One-pot; Suzuki-Miyaura reaction; COUPLING REACTION; CROSS-COUPLINGS; EFFICIENT; FLUORIDE; PHENOLS;

D O I：

10.1002/slct.201802120

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A practical and efficient protocol for the synthesis of biaryl products in good yields by a ligand-free palladium catalyzed Suzuki-Miyaura reaction of aryl fluorosulfates and various arylboron compounds has been developed. Moreover, we report a one-pot tandem method for conversion of phenol derivatives to aryl fluorosulfates, and subsequent cross-coupling to form biaryls.

引用

页码：12287 / 12290

页数：4

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