Structural peculiarities of phosphate glasses for fiber optic applications

被引:1
|
作者
Anan'ev, A [1 ]
Bogdanov, V [1 ]
Maksimov, L [1 ]
Rusan, V [1 ]
Smerdin, S [1 ]
Yanush, O [1 ]
机构
[1] State Opt Inst, St Petersburg 193171, Russia
来源
OPTICAL MATERIALS AND APPLICATIONS | 2005年 / 5946卷
关键词
glass; light scattering losses; fluctuations; ultrasonic velocity;
D O I
10.1117/12.639054
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Alkali phosphate, phosphate-silicate, and phosphate-germanate glasses were studied by means of high-temperature acoustics and Rayleigh-Mandelstam-Brillouin (RMBS) and Raman scattering (RS) spectroscopies. Temperature-temporal dependences of the ultrasound velocity in the glass melts were measured at temperatures up to 1550 degrees C. From the RMBS spectra the Landau-Placzek ratio and frequency shifts were found. A theory of the fluctuations freezing at the cooling of the glass melt was applied to separate the contributions of the frozen-in density and concentration fluctuations to the Rayleigh scattering losses. A comparison was drawn with the losses in silica glass. The RS spectra allowed the identification of the constant-stoichiometry groups. The feasibility of the system xNa(2)O-(40 - x)K2O-30Al(2)O(3)-30P(2)O(5) for the fabrication of low-scattering glasses was ascertained.
引用
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页数:9
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