Decomposition of 1,1-dichloroethene on Pd(111)

被引：6

作者：

Hunka, DE ^{[1
]}

Herman, DC ^{[1
]}

Lormand, KD ^{[1
]}

Jaramillo, DM ^{[1
]}

Land, DP ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

LANGMUIR | 2005年 / 21卷 / 18期

关键词：

D O I：

10.1021/la050645i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The decomposition of 1,1-dichloroethene on Pd(111) is investigated using conventional thermal desorption, laser-induced thermal desorption (LITD), and FT reflection absorption infrared spectroscopy (FT-RAIRS). The decomposition mechanism produces at least three hydrocarbon surface intermediates, including ethylidyne. Thermal desorption results differ between high and low coverages because of relative surface concentrations of Cl and H in combination with kinetic effects.

引用

页码：8333 / 8337

页数：5

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