Syntheses of novel N-[bis(trimethylsilyl)methyl]-1,2-and 1,3-diamines

被引：3
|
作者：
Picard, JP [1 ]
Fortis, F [1 ]
Grelier, S [1 ]
机构：
[1] Univ Bordeaux 1, CNRS, UMR 5802, Chim Organ & Organomet Lab, F-33405 Talence, France
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 686卷 / 1-2期
关键词：
alpha-silylamines; Polyamines; bis-imination reactions; cyanoethylation reactions; caldine;
D O I：
10.1016/S0022-328X(03)00614-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Original N-[bis(trimethylsilyl)methyl]-1,2- and 1,3-diamines of type I were prepared either from bis-imination reaction of 1,2-dicarbonyl compounds with bis(trimethylsilyl)methylamine, BSMA (1) followed by reduction or from cyanoethylation of BSMA followed by reduction of the nitrile group. By varying the conditions of the cyanoethylation reaction bisaddition was obtained allowing to access to 5-[bis(trimethylsilyl)methyl]caldine (8). [graphics] (C) 2003 Elsevier B.V. All rights reserved.
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收藏
页码：306 / 312
页数：7
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