Synthesis and characterization of polymeric Ni(II) complexes of 4-(4-aminobenzyl) benzenamine (abba) and 4-(4-aminophenylthio) benzenamine (aptba) with thiocyanate

被引:1
|
作者
Yu, Wen-Juan [1 ]
Li, Xue-Mei [1 ]
Zhang, Shu-Sheng [1 ]
机构
[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China
关键词
self-assembled nickel polymer; crystal structure; thermal chemical properties;
D O I
10.1080/00958970701266716
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two one-dimensional complexes, [Ni(SCN)(2)(abba)(2)](n) (abba 4-(4-aminobenzyl) benzenamine) (1) and [Ni( SCN)(2)( aptba)(2)](n) (aptba 4-(4-aminophenylthio) benzenamine) (2), were synthesized and characterized by EA, IR, X-ray crystallography and thermal analysis. The single crystal X-ray structural analyses of 1 and 2 show the complexes to be 1D chain polymers as a result of dibenzenamine (dba) bridging. Each Ni is six-coordinate and adopts a slightly distorted octahedral geometry with four N atoms from four dba ligands and two N atoms from two NCS-groups. Adjacent Ni atoms and two dba ligands form a 24-membered macrocycle. Thermogravimetric analysis and differential thermogravimetric analysis of 2 show that the thermal decomposition of 2 includes four transitions.
引用
收藏
页码:2361 / 2367
页数:7
相关论文
共 50 条
  • [31] CONJUGATED SCHIFF BASES SYNTHESIS AND PRELIMINARY CHARACTERIZATION OF 4-(ALKOXYCINNAMYLIDENE)-4'-NITROANILINES
    LIN, YR
    HONG, YLV
    HONG, JL
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1994, 241 : 69 - 76
  • [32] MALDI MS-based analysis of oligosaccharides using 4-(diphenylphosphinyl) benzenamine as non-reductive amination derivatization reagent
    Yang, Xu
    Gan, Jiepeng
    Yuan, Hang
    Chen, Peng
    Liu, Yan
    Jiang, Yuyang
    Liu, Hongxia
    Zhao, Yufen
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2017, 417 : 76 - 82
  • [33] Synthesis and characterization of new polyureas derived from 4-(4′-methoxyphenyl)urazole
    Mallakpour, SE
    Hajipour, AR
    Raheno, H
    JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 85 (06) : 1141 - 1146
  • [34] Synthesis, optical and thermal behaviour of palladium(II) complexes with 4-(4-alkoxy-2-hydroxybenzylideneamino)azobenzene
    Heng, Boon-Teck
    Yeap, Guan-Yeow
    Takeuchi, Daisuke
    JOURNAL OF CHEMICAL SCIENCES, 2013, 125 (06) : 1435 - 1443
  • [35] Synthesis, optical and thermal behaviour of palladium(II) complexes with 4-(4-alkoxy-2-hydroxybenzylideneamino)azobenzene
    BOON-TECK HENG
    GUAN-YEOW YEAP
    DAISUKE TAKEUCHI
    Journal of Chemical Sciences, 2013, 125 : 1435 - 1443
  • [36] Tetrahedral chalcogeno thiocyanate cluster complexes [Re4Q4(SCN)12]4- (Q= S, Se, Te):: synthesis and crystal structures
    Mironov, YV
    POLYHEDRON, 2000, 19 (04) : 437 - 439
  • [37] Synthesis, structural characterization, antimicrobial activities and theoretical investigations of some 4-(4-aminophenylsulfonyl) phenylimino) methyl)-4-(aryldiazenyl) phenol
    Ghasemian, Motaleb
    Kakanejadifard, Ali
    Karami, Tahereh
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2016, 168 : 190 - 198
  • [38] Synthesis and characterization of cerium, thorium, and uranyl complexes with ( E )-4-(4-methoxyphenoxy)-4-oxobut-2-enoic acid
    Liu, Tonghuan
    Duan, Guojian
    Zeng, Zhengzhi
    JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (13) : 2203 - 2211
  • [39] Synthesis and characterization of 4- and 6-coordinate, cationic aluminum complexes.
    Jegier, JA
    Atwood, DA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 403 - INOR
  • [40] Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines
    Dimitrijevic, Teodora
    Novakovic, Irena
    Radanovic, Dusanka
    Novakovic, Sladjana B.
    Rodic, Marko V.
    Andelkovic, Katarina
    Sumar-Ristovic, Maja
    JOURNAL OF COORDINATION CHEMISTRY, 2020, 73 (04) : 702 - 716