Comment on "An explanation for the charge on water's surface" by A. Gray-Weale and J. K. Beattie, Phys. Chem. Chem. Phys., 2009, 11, 10994

被引：10

作者：

Vacha, Robert ^{[1
,2
,3
]}

Horinek, Dominik ^{[4
]}

Buchner, Richard ^{[5
]}

Winter, Bernd ^{[6
,7
]}

Jungwirth, Pavel ^{[1
,2
]}

机构：

[1] Acad Sci Czech Republic, Inst Organ Chem & Biochem, CR-16610 Prague 6, Czech Republic

[2] Ctr Complex Mol Syst & Biomol, Prague 16610 6, Czech Republic

[3] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[4] Tech Univ Munich, Dept Phys, D-85748 Garching, Germany

[5] Univ Regensburg, Inst Phys & Theoret Chem, D-93040 Regensburg, Germany

[6] Helmholtz Zentrum Berlin Mat & Energie, D-12489 Berlin, Germany

[7] BESSY, D-12489 Berlin, Germany

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2010年 / 12卷 / 42期

关键词：

SIMULATIONS; IONS; HYDRATION; DYNAMICS;

D O I：

10.1039/c001492c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gray-Weale and Beattie's rationalization of the negative charge observed on the surface of water in terms of accumulation of OH(-) is based on the supposedly uniquely large dielectric decrement of hydroxide solutions [A. Gray-Weale and J. K. Beattie, Phys. Chem. Chem. Phys., 2009, 11, 10994]. We challenge this rationalization and point to another ion, namely fluoride, which has a comparable dielectric decrement and size and which is repelled from the surface of water.

引用

页码：14362 / 14363

页数：2

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