Crucial role of Ru•••H interactions in the crystal packing of ruthenocene and its derivatives

被引：38
|
作者：
Borissova, Alexandra O. [1 ]
Antipin, Mikhail Yu. [1 ]
Perekalin, Dmirtrii S. [1 ]
Lyssenko, Konstantin A. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
CRYSTENGCOMM | 2008年 / 10卷 / 07期
关键词：
D O I：
10.1039/b716776h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The peculiarities of crystal packing of ruthenocene (eta(5)-C5H5)(2)Ru and its derivatives were investigated by means of high resolution X-ray diffraction analysis of electron density distribution and analysis of the Cambridge Structural Database. The combination of experimental data and statistical treatment made it possible to conclude that the increase of the M center dot center dot center dot Cp separation in ruthenocene and its derivatives leads to the principally different system of intermolecular contacts preventing crystal disorder as compared to 3d-metallocenes.
引用
收藏
页码：827 / 832
页数：6
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