Two new metal coordination polymers containing mixed ligands:: hydrothermal synthesis and crystal structures of [Co2(1,2,4,5-btc)(phen)2(H2O)6] • 2H2O and [Mn3(1,2,4-btc)2(phen)2(H2O)2]n

被引：6
|
作者：
Qi, YF [1 ]
Wang, XL [1 ]
Wang, EB [1 ]
Qin, C [1 ]
Na, H [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 58卷 / 15期
基金：
中国国家自然科学基金;
关键词：
coordination polymers; hydrothermal synthesis; crystal structure; supramolecular network;
D O I：
10.1080/00958970500156803
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Crystallisation of benzene-1,2,4,5-tetracarboxylic acid or benzene-1,2,4-tricarboxylic acid with divalent metal ions of Co, and Mn with 1,10-phenanthroline gives two new coordination solids, [Co-2(C10H2O8)(C12H8N2)(2)(H2O)(6)] center dot 2H(2)O (1) and [Mn-3(C9H3O6)(2)(C12H8N2)(2)(H2O)(2)](n) ( 2). The three-dimensional supramolecular structure of compound 1 is constructed from discrete [Co-2(C10H2O8)(C12H8N2)(2)(OH2)(6)] dimers and isolated water molecules via interesting hydrogen-bonding and pi-pi stacking interactions. Compound 2 has an unusual ( 4, 6) network, and the network is furthermore extended into a three-dimensional supramolecular architecture by the aid of hydrogen bonding and pi-pi stacking interactions.
引用
收藏
页码：1289 / 1297
页数：9
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