A polyhedral oligomeric silsesquioxane functionalized copper trimesate

被引:25
|
作者
Sanil, E. S. [1 ,2 ]
Cho, Kyung-Ho [1 ]
Hong, Do-Young [1 ,2 ]
Lee, Ji Sun [1 ]
Lee, Su-Kyung [1 ]
Ryu, Sam Gon [3 ]
Lee, Hae Wan [3 ]
Chang, Jong-San [1 ]
Hwang, Young Kyu [1 ,2 ,4 ]
机构
[1] Korea Res Inst Chem Technol, Catalysis Ctr Mol Engn, Taejon 305600, South Korea
[2] Univ Sci & Technol, Dept Green Chem, Taejon 305350, South Korea
[3] Agcy Def Dev, Taejon 305600, South Korea
[4] Sungkyunkwan Univ, Dept Chem, Suwon 440476, South Korea
关键词
METAL-ORGANIC FRAMEWORKS; CU-BTC; STABILITY; STORAGE; WATER;
D O I
10.1039/c5cc01928a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A metal-organic framework (MOF), copper trimesate (Cu-3(BTC)(2)), was selectively functionalized with aminopropylisooctyl polyhedral oligomeric silsesquioxane (O-POSS) to make the external surface of Cu-3(BTC)(2) hydrophobic and thereby enhance the stability of the material against humidity. POSS modification was also successfully applied to other MOFs such as MOF-74 and MIL-100.
引用
收藏
页码:8418 / 8420
页数:3
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