Growth mechanism, structure and thermoelectric properties of thermally evaporated Bi2(Te09Se0.1)3 thin films

The growth mechanism, crystal structure, and morphology of thin films with thicknesses d = 16-207 nun prepared by thermal evaporation in vacuum of p-Bi-2(Te09Se0.1)(3) polycrystal on glass substrates were studied using X-ray diffractometry and atomic force microscopy. The obtained polycrystalline thin films were single-phase and homogeneous, had a tetradymite-type structure and a unit cell parameter very close to that of Bi-2(Te09Se0.1)(3) polycrystal but, unlike the initial polycrystal, exhibited n -type conductivity. With increasing d, the grain size and roughness of the thin films increased. It was found that the predominant direction of the crystallite growth was [0 0 iota], but at d larger than similar to 130 nm, along with the reflections from the (0 0 iota) planes, weak reflections from other planes appeared, indicating a certain disorientation of crystallites. An increase in d led to a monotonic increase in the Seebeck coefficient, which indicated the presence of the classical size effect. The obtained data have shown that using a low-cost method of thermal evaporation in vacuum from a single source, one can grow thin Bi-2(Te09Se0.1)(3) films with partial Te -> Se substitution in Bi2Te3 of a sufficiently high quality with preferential orientation [0 0 iota].