Vertically Aligned BCN Nanotubes as Efficient Metal-Free Electrocatalysts for the Oxygen Reduction Reaction: A Synergetic Effect by Co-Doping with Boron and Nitrogen

被引：686

作者：

Wang, Shuangyin ^{[1
]}

Iyyamperumal, Eswaramoorthi ^{[1
]}

Roy, Ajit ^{[2
]}

Xue, Yuhua ^{[1
]}

Yu, Dingshan ^{[1
]}

Dai, Liming ^{[1
]}

机构：

[1] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA

[2] USAF, Thermal Sci & Mat Branch, Mat & Mfg Directorate, Res Lab, Dayton, OH 45433 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 49期

关键词：

doping; electrochemistry; fuel cells; nanotubes; oxygen reduction; DOPED CARBON NANOTUBES; NITRIDE; GROWTH; ARRAYS; NANOPARTICLES; PROPERTY;

D O I：

10.1002/anie.201105204

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A single-compound source of B, C, and N was used for the growth of vertically aligned BCN (VA-BCN) nanotubes (NTs). Owing to a synergetic effect of co-doping of C nanotubes (CNTs) with N and B, the VA-BCN NTs show significantly improved electrocatalytic activity (e.g., current density) for the oxygen reduction reaction compared to undoped VA-CNTs, CNTs doped with only B or N (VA-BCNT, VA-NCNT), and a commercial Pt/C electrocatalyst (see picture). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11756 / 11760

页数：5

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