Supramolecular polymers formed by cinnamoyl cyclodextrins

被引:25
|
作者
Harada, A [1 ]
Miyauchi, M [1 ]
Hoshino, T [1 ]
机构
[1] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Toyonaka, Osaka 5600043, Japan
关键词
supramolecular polymer; cyclodextrin; inclusion complex; host-guest interaction; two-dimensional (2D) NMR; vapor pressure osmometry; host-quest system; inclusion chemistry; molecular recognition;
D O I
10.1002/pola.10831
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
6-Cinnamoyl alpha-cyclodextrin (6-CiO-alpha-CD) and 6-cinnamoyl beta-cyclodextrin (6-CiO-beta-CD) were prepared. 6-CiO-alpha-CD formed intermolecular complexes to give supramolecular oligomers. 6-CiO-P-CD formed insoluble supramolecular complexes in the solid state. The structures of these complexes are discussed. (C) 2003 Wiley Periodicals, Inc.
引用
收藏
页码:3519 / 3523
页数:5
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