Energy-transfer process in rare-earth-ion doped SrTiO3

被引:0
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作者
Okamoto, S [1 ]
Tanaka, S [1 ]
Yamamoto, H [1 ]
机构
[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Ikoma, Nara 6300101, Japan
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中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Enhancement of emission intensity of rare-earth-ion doped SrTiO3 by Al addition has been investigated. In the case of Pr3+ and Tb3+, addition of 23-mol% Al intensifies emission by more than 200 times. In contrast, the addition of 20 mol% Al intensifies emission at most by three times in the case of other rare-earth ions. The temperature dependence of PL spectra shows that the energy transfer from carriers to Pr3+ or Tb3+ ions is much more efficient than that to other rare-earth ions in SrTiO3. It can be speculated that the energy transfer in SrTiO3 :Pr3+ or Tb3+ occurs from carriers to Pr3+ or Tb3+ ion via 4f-5d transitions, which are much higher in oscillator strength than 4f-4f transitions.
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页码:356 / 359
页数:4
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