Electrocatalytic asymmetric reduction of ethyl benzoylformate on bimetallic Ag-Cu cathodes

被引：5

作者：

Wang, Shuo ^{[1
]}

Shi, Yi ^{[1
]}

Hou, Yue ^{[1
]}

Shan, Si-Li ^{[1
]}

Wang, Huan ^{[1
]}

Lu, Jia-Xing ^{[1
]}

机构：

[1] East China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Sch Chem & Mol Engn, Shanghai 200062, Peoples R China

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 2020年 / 50卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Ag-Cu NPs; Asymmetric electroreduction; Cinchonidine; Ethyl benzoylformate; Ethyl mandelate; ENANTIOSELECTIVE HYDROGENATION; CATALYSTS; PLATINUM;

D O I：

10.1007/s10800-020-01449-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Ag-Cu bimetallic nanoparticles were synthesised and used as cathode materials for the asymmetric electroreduction of ethyl benzoylformate. The reaction induced by cinchonidine was conducted in an undivided cell to produce the optically active ethyl mandelate. We obtained ethyl mandelate with 54% enantiomeric excess and 42% yield under the optimal conditions. Graphic abstract

引用

页码：973 / 978

页数：6

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