Electrocatalytic asymmetric reduction of ethyl benzoylformate on bimetallic Ag-Cu cathodes

被引：5

作者：

Wang, Shuo ^{[1
]}

Shi, Yi ^{[1
]}

Hou, Yue ^{[1
]}

Shan, Si-Li ^{[1
]}

Wang, Huan ^{[1
]}

Lu, Jia-Xing ^{[1
]}

机构：

[1] East China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Sch Chem & Mol Engn, Shanghai 200062, Peoples R China

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 2020年 / 50卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Ag-Cu NPs; Asymmetric electroreduction; Cinchonidine; Ethyl benzoylformate; Ethyl mandelate; ENANTIOSELECTIVE HYDROGENATION; CATALYSTS; PLATINUM;

D O I：

10.1007/s10800-020-01449-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Ag-Cu bimetallic nanoparticles were synthesised and used as cathode materials for the asymmetric electroreduction of ethyl benzoylformate. The reaction induced by cinchonidine was conducted in an undivided cell to produce the optically active ethyl mandelate. We obtained ethyl mandelate with 54% enantiomeric excess and 42% yield under the optimal conditions. Graphic abstract

引用

页码：973 / 978

页数：6

共 50 条

[1] Electrocatalytic asymmetric reduction of ethyl benzoylformate on bimetallic Ag–Cu cathodes
Shuo Wang
Yi Shi
Yue Hou
Si-Li Shan
Huan Wang
Jia-Xing Lu
Journal of Applied Electrochemistry, 2020, 50 : 973 - 978
[2] Formation of Ag-Cu bimetallic hydrosols by the reduction of the solid precursors
Bokshits, Yu. V.
Shevchenko, G. P.
Gurin, V. S.
Ponyavina, A. N.
Rakhmanov, S. K.
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2007, 27 (5-8): : 1149 - 1153
[3] Synthesis and Application of Ag-Cu Bimetallic Dendrites
Kang Ya-Rong
Chen Fu-Yi
ACTA PHYSICO-CHIMICA SINICA, 2013, 29 (08) : 1712 - 1718
[4] Ag-Cu Bimetallic Nanoparticles as Efficient Oxygen Reduction Reaction Electrocatalysts in Alkaline Media
Verma, Alkadevi
Gupta, Rajeev Kumar
Shukla, Madhulata
Malviya, Manisha
Sinha, Indrajit
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2020, 20 (03) : 1765 - 1772
[5] ASYMMETRIC REDUCTION OF ETHYL BENZOYLFORMATE WITH A CHIRAL NADH MODEL-COMPOUND
INOUYE, Y
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 180 (AUG): : 13 - ORGN
[6] Green synthesis of antibacterial bimetallic Ag-Cu nanoparticles for catalytic reduction of persistent organic pollutants
Ismail, Muhammad
Khan, M. I.
Khan, Shahid Ali
Qayum, Mughal
Khan, Murad Ali
Anwar, Yasir
Akhtar, Kalsoom
Asiri, Abdullah M.
Khan, Sher Bahadar
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2018, 29 (24) : 20840 - 20855
[7] Bimetallic Ag-Cu nanosheets assembled flower-like structure for oxygen reduction reaction
Chen, Jianan
Wang, Zhenyu
Mao, Jianjun
Liu, Chang
Chen, Yue
Lu, Zhouguang
Feng, Shien-Ping
JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 856
[8] Ag-Cu bimetallic nanocatalysts for p-nitrophenol reduction using a green hydrogen source
Verma, A. D.
Pal, Shaili
Verma, Pratibha
Srivastava, Vandana
Mandal, R. K.
Sinha, I.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2017, 5 (06): : 6148 - 6155
[9] Formation and evolution of nanoporous bimetallic Ag-Cu alloy by electrochemically dealloying Mg-(Ag-Cu)-Y metallic glass
Li, Ran
Wu, Na
Liu, Jijuan
Jin, Yu
Chen, Xiao-Bo
Zhang, Tao
CORROSION SCIENCE, 2017, 119 : 23 - 32
[10] Fine structure of Ag-Cu bimetallic nanoparticles in silicate glass
Yang, X. (yangxc@tongji.edu.cn), 2012, Chinese Ceramic Society (40):

← 1 2 3 4 5 →