Push-Pull Amino Succinimidyl Ester Thiophene-Based Fluorescent Dyes: Synthesis and Optical Characterization

被引：22

作者：

Sotgiu, Giovanna ^{[1
]}

Galeotti, Matteo ^{[2
]}

Samori, Cristian ^{[1
]}

Bongini, Alessandro ^{[3
]}

Mazzanti, Andrea ^{[4
]}

机构：

[1] Consiglio Nazl Ric CNR ISOF, I-40129 Bologna, Italy

[2] Mediteknology Srl, I-40129 Bologna, Italy

[3] Univ Bologna, Dept Chem G Ciamician, I-40122 Bologna, Italy

[4] Univ Bologna, Dept Organ Chem A Mangini, I-40136 Bologna, Italy

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 28期

关键词：

dyes/pigments; fluorescent probes; oligothiophenes; singlet oxygen; sulfine; COPPER-CATALYZED AMINATION; AZO DYES; DONOR; OLIGOTHIOPHENES; CHROMOPHORES; FLUOROPHORES; BITHIOPHENE; DESIGN; BRIGHT;

D O I：

10.1002/chem.201100142

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The design and synthesis of new fluorescent dyes with emission range at 490-650 nm are described. Their structural and electronic properties have been characterized by both experimental techniques and quantum-chemical calculations. The chromophores are donor-pi-bridge-acceptor push-pull compounds with a pi bridge of phenyl and thiophene rings and their combination. Compared with previous thiophene fluorophores, these dyes show significant redshift in the absorption and emission spectra and offer compact, red-emitting fluorophores. The dyes have amino succinimidyl active ester and can be readily conjugated to proteins, polymers and other amino-group-containing materials.

引用

页码：7947 / 7952

页数：6

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