The determination of the integral enthalpies of mixing of liquid Au-In-Sn alloys and the enthalpy of formation of the Au4In3Sn3 compound

被引：2
|
作者：
Watson, A. [1 ]
Borzone, G. [2 ]
Parodi, N. [2 ]
Cacciamani, G. [2 ]
机构：
[1] Univ Leeds, Inst Mat Res, Sch Proc Environm & Mat Engn, Leeds, W Yorkshire, England
[2] Univ Genoa, Dept Chem & Ind Chem, I-16146 Genoa, Italy
来源：
THERMOCHIMICA ACTA | 2010年 / 510卷 / 1-2期
基金：
英国工程与自然科学研究理事会;
关键词：
High temperature calorimetry; Alloy thermochemistry; Enthalpy of formation; Enthalpy of mixing; Lead-free solders;
D O I：
10.1016/j.tca.2010.06.018
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
With a view to modelling the Au-In-Sn alloy system, the enthalpies of mixing of liquid Au-In-Sn alloys have been measured as a function of Au content by drop calorimetry at 609 degrees C for constant In:Sn ratios of 1:1, 1:3 and 3:1. For each of the three sections studied, the enthalpies of mixing were exothermic. In addition, the enthalpy of formation of the ternary Au4In3Sn3 at 298 K was measured both by direct-reaction calorimetry and by tin-solution calorimetry. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：24 / 31
页数：8
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