Synthesis, structure, and magnetic properties of a tetranuclear copper(fII) complex with a triazenido ligand

被引：4
|
作者：
Li, Wei [1 ]
Tan, Xing-Wu [1 ]
Lei, Wen-Jun [1 ]
Zhan, Shu-Zhong [1 ]
Cao, De-Rong [1 ]
机构：
[1] S China Univ Technol, Coll Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 2010年 / 35卷 / 07期
基金：
美国国家科学基金会;
关键词：
MOLECULAR-STRUCTURE; BINUCLEAR; CHEMISTRY; CRYSTAL; MODELS;
D O I：
10.1007/s11243-010-9401-y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of methyl anthranilate, sodium nitrite, and 2-aminopyridine produces a triazenide, namely, 1-[(2-carboxymethyl) benzene]-3-[2-pyridine] triazene (HL). In the presence of Et3N, the reaction of HL and CuCl2 center dot 2H(2)O gives a mu(4)-oxo-bridged tetranuclear copper(II) complex [Cu4OL3Cl3]center dot 1.5THF (1 center dot 1.5THF), which has been characterized by X-ray crystallography and magnetic susceptibility measurements.
引用
收藏
页码：835 / 839
页数：5
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