Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds

被引：20
|
作者：
Huo, Jingfeng [1 ]
Xue, Yazhen [1 ]
Wang, Jianbo [1 ,2 ]
机构：
[1] Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 86期
关键词：
UNACTIVATED TERMINAL ALKENES; AMINOBORATION; INSERTION; ESTERS; ELECTROPHILES; NITROGEN; BONDS;
D O I：
10.1039/c8cc07764a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Cu(I)-catalyzed aminoborylation reaction of styrenes is reported. In this transformation, diazo compounds are used as the electrophilic amination agent. The in situ generated benzylcopper species is trapped by the electrophilic nitrogen terminus of the diazo substrate to afford borylated hydrazones in a regioselective manner.
引用
收藏
页码：12266 / 12269
页数：4
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