Electrochemical oxidation of organic, organometallic, and coordination compounds. Polarization effect in radical cations

被引：8

作者：

Novikova, O. V. ^{[1
]}

Kuznetsova, O. V. ^{[1
]}

Egorochkin, A. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2007年 / 77卷 / 09期

关键词：

D O I：

10.1134/S1070363207090174

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Half-wave potentials of electrochemical oxidation of 24 reaction series X-B-R-C depend on the inductive, resonance, and polarization effects of substituents X. The polarization effect was not taken into account previously. In X-B-R-C(center dot+) radical cations, the contribution of the polarization effect increases with decreasing size of bridge B linking X with the reaction center R-C and can reach 30%.

引用

页码：1601 / 1609

页数：9

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