An Electrochemical Approach to Study Bis-coordinated Copper/Tebuconazole Complexes

被引：0

作者：

Jakl, Michal ^{[1
]}

Dytrtova, Jana Jaklova ^{[2
]}

Cadkova, Eva ^{[1
]}

机构：

[1] Czech Univ Life Sci Prague, Fac Agrobiol Food & Nat Resources, Dept Agroenvironm Chem & Plant Nutr, Kamycka 129, Prague 16521, Czech Republic

[2] Inst Organ Chem & Biochem, Prague, Czech Republic

来源：

MODERN ELECTROCHEMICAL METHODS XXXI | 2011年

关键词：

Pesticides; stability constant; stoichiometry; DPASV; pseudopolarography; FUNGICIDE TEBUCONAZOLE; STABILITY-CONSTANTS; HEAVY-METALS; SOIL; VOLTAMMETRY; OXIDATION; COPPER;

D O I：

暂无

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The stability and stoichiometry of leading complex in the model system of copper nitrate and tebuconazole (Teb) were evaluated. The successive formation constant for bis-coordinated Cu-Teb species (involved in peak with potential approx. -250 mV) was measured; beta(0) = 7.61 +/- 0.10. The pseudopolarographic measurement indicated the consecutive loss of NO3- group and Cu reduction in more negative accumulation potentials. The structure of an original bis-coordinated species [Cu(II)NO3(Teb)(2)](+) was calculated.

引用

页码：64 / 68

页数：5

共 50 条

[21] COPPER(II) COMPLEXES WITH AN APICALLY COORDINATED THIOETHER GROUP
SAKURAI, T
NAKAHARA, A
INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1981, 55 (06): : 157 - 160
[22] Weakly Coordinated Zinc and Aluminum σ-Complexes of Copper(I)
Nako, Adi E.
Tan, Qian Wen
White, Andrew J. P.
Crimmin, Mark R.
ORGANOMETALLICS, 2014, 33 (11) : 2685 - 2688
[23] Structural and electrochemical study of copper complexes derived from dehydroacetic acid
Djedouani, Amel
Massika, Chaouche
Beghidja, A.
Beghidja, C.
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C523 - C523
[24] A SPECTROSCOPIC AND ELECTROCHEMICAL STUDY OF SOME COPPER(II) TETRAAZA MACROCYCLIC COMPLEXES
ROE, SP
HILL, JO
MAGEE, RJ
MONATSHEFTE FUR CHEMIE, 1987, 118 (04): : 463 - 476
[25] EPR AND ELECTROCHEMICAL STUDY OF COPPER-COMPLEXES WITH PHENANTHROLINES AND CINNAMATE LIGANDS
ZORODDU, MA
PILO, MI
SEEBER, R
POGNI, R
BASOSI, R
INORGANICA CHIMICA ACTA, 1991, 184 (02) : 185 - 189
[26] Electrochemical synthesis of copper nitrile complexes
Günther, M
Schäfer, W
Stettler, A
Hartung, H
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (03): : 655 - 660
[27] ELECTROCHEMICAL BEHAVIOR OF COPPER - EDTA COMPLEXES
HIGGINS, GW
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1970, 117 (03) : C122 - &
[28] Electrochemical behaviour of alkaline copper complexes
Aravinda C.L.
Mayanna S.M.
Muralidharan V.S.
Aravinda, C.L., 2000, Indian Acad of Sciences, Bangalore, India (112) : 543 - 550
[29] Electrochemical synthesis of tricyanomethyl copper complexes
Kamte, MF
Baumeister, U
Schäfer, W
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (11): : 1919 - 1924
[30] Electrochemical behaviour of alkaline copper complexes
Aravinda, CL
Mayanna, SM
Muralidharan, VS
PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 2000, 112 (05): : 543 - 550

← 1 2 3 4 5 →