An efficient combination of Zr-MOF and microwave irradiation in catalytic Lewis acid Friedel-Crafts benzoylation

被引：50

作者：

Doan, Tan L. H. ^{[1
]}

Dao, Thong Q. ^{[1
]}

Tran, Hai N. ^{[1
]}

Tran, Phuong H. ^{[1
]}

Le, Thach N. ^{[1
]}

机构：

[1] Vietnam Natl Univ, Univ Sci, Deparment Organ Chem, Fac Chem, Hochiminh City 721337, Vietnam

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 18期

关键词：

METAL-ORGANIC FRAMEWORKS; TRIFLUOROMETHANESULFONIC ACID; HETEROGENEOUS CATALYST; AROMATIC-COMPOUNDS; ACYLATION; CONVERSION; TRANSFORMATIONS; PHOTOCATALYSTS; ADSORPTION; TRIFLATE;

D O I：

10.1039/c6dt00827e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A zirconium-based metal-organic framework, an effective heterogeneous catalyst, has been developed for the Friedel-Crafts benzoylation of aromatic compounds under microwave irradiation. Constructed by a Zr(IV) cluster and a linker 1,4-bis(2-[4-carboxyphenyl]ethynyl) benzene (H2CPEB), the MOF, possessing large pores and high chemical stability, was appropriate for the enhancement of Lewis acid activity under microwave irradiation. The reaction studies demonstrated that the material could give high yields for a few minutes and maintain its reactivity and structure over several cycles.

引用

页码：7875 / 7880

页数：6

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