Many-body interactions between particles in a polydisperse polymer fluid

被引:7
|
作者
Woodward, Clifford E. [1 ]
Forsman, Jan [2 ]
机构
[1] Univ New S Wales, Univ Coll, Sch Phys Environm & Math Sci, ADFA, Canberra, ACT 2600, Australia
[2] Lund Univ, Ctr Chem, S-22100 Lund, Sweden
来源
JOURNAL OF CHEMICAL PHYSICS | 2012年 / 136卷 / 08期
关键词
approximation theory; many-body problems; phase diagrams; polymers; PHASE-BEHAVIOR; MIXTURES; MODEL;
D O I
10.1063/1.3685834
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We use a continuum chain model and develop an analytical theory for the interaction between many spheres immersed in a fluid of ideal polydisperse polymers. Assuming local spherical symmetry of the polymer field about each particle, combined with a local approximation, compact expressions are derived for the many-body interaction between the spheres. We use a mean-field approximation to investigate the fluid-fluid phase diagram for the mixture. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.3685834]
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页数:5
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