Sequence-controlled molecular layers on surfaces by thiol-ene chemistry: synthesis and multitechnique characterization

被引：1

作者：

Llevot, A. ^{[1
]}

Steinmueller, S. O. ^{[2
]}

Bitterer, B. ^{[1
]}

Ridder, B. ^{[1
]}

Berson, J. ^{[3
,4
]}

Walheim, S. ^{[3
,4
]}

Schimmel, T. ^{[3
,4
]}

Braese, S. ^{[1
,5
]}

Scheiba, F. ^{[2
]}

Meier, M. A. R. ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, Mat Wissensch Zentrum MZE, Inst Organ Chem, Bldg 30-48 Str Forum 7, D-76131 Karlsruhe, Germany

[2] Karlsruhe Inst Technol, Inst Appl Mat, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany

[3] Karlsruhe Inst Technol, Inst Appl Phys, Wolfgang Gaede Str 1, D-76131 Karlsruhe, Germany

[4] Inst Nanotechnol INT, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany

[5] Karlsruhe Inst Technol, Inst Toxicol & Genet, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany

来源：

POLYMER CHEMISTRY | 2017年 / 8卷 / 38期

关键词：

SELF-ASSEMBLED MONOLAYERS; ION MASS-SPECTROMETRY; BY-LAYER; CLICK CHEMISTRY; ULTRATHIN FILMS; CHEMICAL DERIVATIZATION; MULTILAYER FILMS; TOF-SIMS; DEPOSITION; XPS;

D O I：

10.1039/c7py01515a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Silicon surfaces were functionalized by thiol-ene chemistry using sequential reactions of different alpha,omega-dienes and alpha,omega-dithiols bearing marker moieties. A system of six individual layers was achieved and exhaustively characterized by combining independent techniques such as X-ray Photoelectron Spectroscopy, Time-of-Flight Secondary Ion Mass Spectrometry and Atomic Force Microscopy using a molecular ruler system.

引用

页码：5824 / 5828

页数：5

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