Synthesis and structure of hexaaquacobalt bis(2-methyl-1H-imidazol-3-ium) tetraaquabis(benzene-1,3,5-tricarboxylato-κO)cobalt

被引：1

作者：

Velazquez-Garcia, Jose de Jesus ^{[1
]}

Techert, Simone ^{[1
,2
]}

机构：

[1] DESY, Notkestr 85, D-22607 Hamburg, Germany

[2] Georg August Univ Gottingen, Inst Rontgenphys, Friedrich Hund Pl 1, D-37077 Gottingen, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2022年 / 78卷

关键词：

crystal structure; hexaaqua-cobalt; 2-methylimidazole; 1,3,5-benzene tricarboxylic acid; GRAPH-SET ANALYSIS; TRANSITION; COMPLEXES; PATTERNS;

D O I：

10.1107/S2056989022007046

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, (C4H7N2)(2)[Co(H2O)(6)][Co(C9H3O6)(2)(H2O)(4)] (1), was synthesized from cobalt(II) chloride, 1,3,5-benzene tricarboxylic acid (Hbtc) and 2-methyl-imidazole (H-2mIm) under ambient conditions. The structure of 1 is here reported and compared with the parent complex hexaaquacobalt bis(1H-imidazol-3-ium) tetraaquabis(benzene-1,3,5-tricarboxylato)cobalt (2).

引用

页码：814 / +

页数：10

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